Новые подходы к синтезу гетерополиядерных комплексов

Скопенко, В., & Кокозей, В. (2007). Новые подходы к синтезу гетерополиядерных комплексов. Вісник Київського національного університету імені Тараса Шевченка. Хімія, (44), 27–34.

The idea of direct synthesis of coordination compounds - use of elemental metals or their oxides as starting materials-has been developed into "salt route", "ammonium salt route", "direct template synthesis" and "direct permanganate" methods to synthesize heteropolynuclear complexes of transition metals. The advantages of this approach in obtaining of heteropolynuclear complexes are shown taking complexes of transition metals with aminoalcohols ligands, ethylenediamine and their derivatives as an example. The results of the X-ray crystal structure analysis of the most interesting complexes are presented. The perspectives of the development ofthe direct synthesis methods for preparation of heteropolynuclear complexes are discussed.