Synthesis and Investigation of Polymerization Properties of Methacrylic Monomers with Chiral Fragments

Тип публікації :
Стаття
Дата випуску :
2015
Автор(и) :
Syromyatnikov, Vladimir
Nadtoka, Oksana
Мова основного тексту :
Англійська
eKNUTSHIR URL :
DOI :
Журнал :
Том :
3
Випуск :
2
ISSN :
2312-3222
Початкова сторінка :
101
Кінцева сторінка :
108
Цитування :
[APA 7] Syromyatnikov, V., & Nadtoka, O. (2015). Synthesis and Investigation of Polymerization Properties of Methacrylic Monomers with Chiral Fragments. French-Ukrainian Journal of Chemistry, 3(2), 101–108. https://doi.org/10.17721/fujcV3I2P101-108
[ДСТУ] Syromyatnikov V., Nadtoka O. Synthesis and Investigation of Polymerization Properties of Methacrylic Monomers with Chiral Fragments. French-Ukrainian Journal of Chemistry. 2015. Vol. 3, no. 2. P. 101—108. DOI: 10.17721/fujcV3I2P101-108 (date of access: 25.07.2026).
Methacrylic monomers containing chiral moieties and azobenzene derivatives were synthesized. As the chiral component was used menthol. The polymerization properties of monomer (5-methyl-2- (1-methyl)cyclohexanol with azomonomers were studied and the reactivity ratios as well as parameters Q and e characterizing the activity of the obtained monomers have been calculated. On basis of the synthesized monomers were synthesized chiral-photochromic copolymers and their absorption spectra were studied. It was shown that in the copolymers absorption spectra the absorption maxima are in the wavelength region of 340-360 nm and correspond to trans-form of azo fragments
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