Reaction of 1-aminoisoindole with 1,4-naphthoquinone and study of the product by spectroscopic methods.
Тип публікації :
Стаття
Дата випуску :
2018
Автор(и) :
Levkov, Igor
Yegorova, Tetyana
Kysil, Andriy
Vedrenne, Marc
Voitenko, Zoia
Мова основного тексту :
Англійська
eKNUTSHIR URL :
Том :
6
Випуск :
2
ISSN :
2312-3222
Початкова сторінка :
27
Кінцева сторінка :
31
Цитування :
[APA 7] Levkov, I., Yegorova, T., Kysil, A., Vedrenne, M., & Voitenko, Z. (2018). Reaction of 1-aminoisoindole with 1,4-naphthoquinone and study of the product by spectroscopic methods. French-Ukrainian Journal of Chemistry, 6(2), 27–31. https://doi.org/10.17721/fujcV6I2P27-31
[ДСТУ] Reaction of 1-aminoisoindole with 1,4-naphthoquinone and study of the product by spectroscopic methods. / I. Levkov et al. French-Ukrainian Journal of Chemistry. 2018. Vol. 6, no. 2. P. 27—31. DOI: 10.17721/fujcV6I2P27-31 (date of access: 18.07.2026).
In our previous researches we have shown, that 1-aminoisoindole, which exists predominantly in isoindoline tautomeric form, can undergo [4+2]-cycloaddition reactions with maleimides according to the Curtin-Hammet principle. We continued to study this reaction, but with another dienophile – 1,4-naphtoquinone. In this case, the reaction does not stop when the bis-Michael adduct is obtained, but continues with the formation of a more complex compound, the structure of which we have studied by two-dimensional NMR spectroscopic methods.
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