En route to a dianilinyl-substituted carbo-cyclohexadiene with promising electrical properties
Тип публікації :
Стаття
Дата випуску :
2015
Автор(и) :
Lozynskyi, Oleg
Barthes, Cécile
Rives, Arnaud
Maraval, Valérie
Voitenko, Zoia
Chauvin, Remi
Мова основного тексту :
Англійська
eKNUTSHIR URL :
Том :
3
Випуск :
1
ISSN :
2312-3222
Початкова сторінка :
46
Кінцева сторінка :
52
Цитування :
[APA 7] Lozynskyi, O., Barthes, C., Rives, A., Maraval, V., Voitenko, Z., & Chauvin, R. (2015). En route to a dianilinyl-substituted carbo-cyclohexadiene with promising electrical properties. French-Ukrainian Journal of Chemistry, 3(1), 46–52. https://doi.org/10.17721/fujcV3I1P46-52
[ДСТУ] En route to a dianilinyl-substituted carbo-cyclohexadiene with promising electrical properties / O. Lozynskyi et al. French-Ukrainian Journal of Chemistry. 2015. Vol. 3, no. 1. P. 46—52. DOI: 10.17721/fujcV3I1P46-52 (date of access: 25.07.2026).
The macro-aromatic carbo-benzene core para-disubstituted by 4-anilinyl groups is known to be an efficient single-molecule conductor, exhibiting a conductance of 106 nS measured by the scanning tunneling microscopy-break junction technique. The linear carbo-butadiene analogue bearing the same anilinyl substituents was found to be less efficient, with a conductance of 2.7 nS. The reason of this difference could be elucidated through the study of the charge transport properties of a cyclically locked carbo-butadiene core in a carbo-cyclohexadiene derivative. In this paper, advances in the synthesis of this challenging dianilinyl-substituted carbo-cyclohexadiene are presented.
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