Effect of ligand substitution in [Fe(H-trz)2(trz)]BF4 spin crossover nanoparticles

Suleimanov, I., Sanchez Costa, J., Molnár, G., Salmon, L., Fritsky, I., Bousseksou, A. (2015). Effect of ligand substitution in [Fe(H-trz)2(trz)]BF4 spin crossover nanoparticles. French-Ukrainian Journal of Chemistry, 3(1), 66–72. https://doi.org/10.17721/fujcV3I1P66-72

Spin crossover iron(II) 1,2,4-triazole-based coordination compounds in the form of nanoparticles were prepared using a reverse microemulsion technique. Ligand substitution approach was applied to decrease the spin crossover temperature towards room temperature in the well-known [Fe(Htrz)2(trz)]BF4 complex. The compositions of the particles were determined by elemental analysis and thermogravimetry. The morphology was monitored by transition electron microscopy (TEM). The effect associated with the ligand substitution was investigated by optical and magnetic measurements. Transition temperature has been reduced by 33 K comparing the unsubstituted sample to that with 5 % substitution.