Aromatic Structure Influence on the Selectivity of Substituted Methacryloylaminophenylmethacrylates Free-Radical Polymerization

Vretik, L. O., Nikolaeva, O. A., Zagniy, V. V., Syromyatnikov, V. G. (2013). Aromatic Structure Influence on the Selectivity of Substituted Methacryloylaminophenylmethacrylates Free-Radical Polymerization. French-Ukrainian Journal of Chemistry, 1(1), 100–104.

A new dimethacrylic monomer with biphenylbenzoate-type aromatic core was tested to the possibility to carry out its selective homopolymerization under conditions of thermoinitiated radical polymerization in DMF solution. The kinetics of thermo-induced radical homopolymerization of this monomer as well as some model compounds were studied by dilatometry. The preferring polymerization of O-methacryloyl double bond was proved by 1H NMR spectroscopy.