Baglai, IaroslavIaroslavBaglaiRamos-Ortiz, GabrielGabrielRamos-OrtizMaldonado, José-LuisJosé-LuisMaldonadoVoitenko, ZoiaZoiaVoitenkoMaraval, ValérieValérieMaravalChauvin, RemiRemiChauvin2026-06-262026-06-262018Baglai, I., Ramos-Ortiz, G., Maldonado, J., Voitenko, Z., Maraval, V., Chauvin, R. (2018). A difluorenyl-carbo-cyclohexadiene: prospective chromophore for two-photon absorption. French-Ukrainian Journal of Chemistry, 6(2), 9–17. https://doi.org/10.17721/fujcV6I2P9-1710.17721/fujcV6I2P9-17https://ir.library.knu.ua/handle/15071834/25495For the purpose of outlining structure-property relationships for two-photon absorption (2PA), a "s-locked" carbo-cyclohexadiene with two fluorenyl substituents has been envisaged for comparison with previously studied aromatic carbo-benzene and non-aromatic carbo-quinoid congeners. A representative where the C10-π-conjugated fluorenyl moieties are also connected by a C8-π-insulating 3,6‐dimethoxy‐3,6‐bis(trifluoromethyl)octa‐1,4,7‐triyn-1,8-diyl edge has thus been synthesized in four steps from known C8F triyne and C10 triynyldial, through a [8F+10] cyclization process. In spite of a relatively strong absorbance (e = 84 800 L.mol-1.cm-1 at 634 nm), the non-vanishing green fluorescence (at 533 nm) of the chromophore should allow measurements of the 2PA cross section by both the TPEF and Z-scan methods.enAlkyneButatrieneCarbo-merTwo-photon absorptionFluoreneСтаття