Gorichko, MarianMarianGorichko2026-06-252026-06-252025-08-20Gorichko, M. (2025). Beckmann Fragmentation of Camphor-4-carboxylic and Camphor-4-acetic Acid Oximes. French-Ukrainian Journal of Chemistry, 13(1), 104–109. https://doi.org/10.17721/fujcV13I1P104-10910.17721/fujcV13I1P104-109https://ir.library.knu.ua/handle/15071834/25293A mild and efficient recyclization reaction of bornanone-4-carboxylic and bornanone-4-acetic acid oximes in aqueous hydrochloric acid has been developed. Beckmann fragmentation followed by hydrolysis provides a straightforward method for the preparation and isolation of functionalized [2.2.1] and [3.3.0] bicyclic lactones in nearly quantitative yields. These simple transformations offer the opportunity to obtain a wide range of more complex functionalized bicyclic terpenoids on a large-scale, starting from readily available camphor derivatives.enBeckmann fragmentationintramolecular lactonizationcamphorcarbocationcarboxylic acidСтаття